I've said this before and I'll say it again. The residual cooper in the silicone is NOT a renewable source. The amount that can leach out eventualy has to run out, if not resupplied. If the amount that can leach out is substantial, it will be a short time before it is deplenished. If it a trace amount, and I'm talking a minute amount, then it should not build up faster than your water changes would remove it.
I have used tanks that have had copper in them without any problems. I have argued this point with many people and not one has given me any facts as to how much or for how long silicone will leach copper. All I've ever got in reply is" well this or that died because I used a tank that had copper in it at one time". Things die in our tanks all the time without a clue as to the cause, so the copper theory does'nt fly in my book.
The point that no one has given me proof of how much does actually leach out does'nt make me right either, but I DO acknowledge that copper can leach out of the silicone. I just don't think it makes the tank unusable as a reef forever.