It seems to be a thing with the name of "Bob" and bad advice. It must be a molecular attraction
. The rudeness must come from the sponge, as PLB was never rude IMO.
Regarding the initial question I believe that the guy that asked it is a noob, so he does need a chemistry 101 (not from SB). So here it goes:
pH is tied to Alk and CO2. Actually, for a given Alk and CO2 concentration, there should be a fixed pH (as shown in Randy's article). If the pH is low, either Alk is low or CO2 is high. Your first task is to figure out which of them is off, the second is to fix it.
For Alk, the easiest way is to measure is using a good kit. I only know a good one - Salifert and a bad one: RedSea. If it's off (i.e., low) then you need to add some buffer. Usually, when Alk is low, Ca is low as well, so you normally need to also add Ca.
For CO2, you can try to get the sample and aerate it
outside the house (maybe for 1 hour with an airstone on the deck). Then measure the pH again. If it increased you're high on CO2 in the tank. Now there are two posibilities:
1) - either the CO2 in the house is ok (normal or only slightly up) and you don't have a good exchange of gas. You can fix that first by getting a skimmer, then by using an overflow or a powerhead that produces surface agitation.
2) or the CO2 in the house is on the high side and then surface agitation will not help. In this case you should either bring air from outside (either in the entire house or just for the tank) or get somebody that eats CO2 in the tank. That somebody can be kalkwasser, or, even better, (...drums....),
macroalgae, known to PLB as "plant life". For this very reason, many people run their sumps filled with macroalgae on a reverse light cycle (i.e., ligts in the sump are on when lights in the tank are off and the other way around).
Finally, I'd make sure that my pH measurements are good by testing with a different method (your LFS should do that for free).
I think this summarizes the technical part. For the social part... I'll refrain myself this time
.
M.