Well I sure appriciate the feedback guys, you I know I love to type it if people love to read it...
I dose my picos in a little bit different manner than larger nano setups. Acid binding of ALK components is particularly pronounced in sub-gallon designs, so on that note I add C_Balance (one set lasting a year or more) 3 cc's of calcium on Mon, Wed, Fri and ALK (bottle B) 4 cc's Tues, Thurs and some Sundays if I'm at home. I use an insulin syringe to dose the components through the access hole drilled into the custom lid.THis is sufficent ion balance to meet the calcification requirements of any coral that can physically fit into the tank. I use this method to keep SPS in the pico reef design. Wait till I post some update pics of the system currently, it's the most densely stocked pico reef to date.
More fine balance: any of these above-stated doses, given in the afternoon, can kill the system and cause immediate tissue peeling of the stony corals. Dosing must be done in the morning before the photosynthetic peak of the system at hand. I have done this before and its devastating! pH of the system is highest in the afternoon and evening, so adding anything that boosts pH is immediate grounds for overdosing and system mortality. Dosing larger nanos in the afternoon is more likely to cause precipitation events and maybe not immediate death--this phenomena is more pronounced in sub gallon ecosystems.