Chris, removing a sick fish from a tank like yours requires artistry and luck. Not to mention help from the gods. Damn near impossible, in other words. It is important to q-tank all new fish, I agree, but once a fish is in such a tank, it's important to monitor tank parameters and try to prevent problems from arising. Cuz, once they do, you are S.O.L.
Adjusting the pH by means of a buffer, and then testing the water, is how you can match the pH. After a few trys, it becomes easier. Add a tiny bit of buffer at a time, and keep testing, until your bucket pH matches the tank. Keep track of how much buffer you added, for the next time
There are reef safe products you can add to reef tanks, but I have not heard of anyone having success, perhaps because they have not found the cause of the stress in the first place and fixed the problem, but it's hard to say if that would make a difference, I have not studied this.
Your only other hope is to lower the salinity, I prefer not to advise that, since it's hard to say what the effect would be on your corals and inverts. Some folks do this, however. Lower your specific gravity to around 1.016 or so...do it slowly, over a period of days, and jack up the heat to around 84. This is not my solution, just A solution.
I would love to try one of the new acrylic traps made to catch reef fish, it would certainly be helpful when it comes time to isolate a fish for medication purposes.