When you test the pH of RO/DI water, you are usually testing the pH of the test kit itself... Also RO/DI water does lean toward the Acid side cause of CO2 that has been absorbed by the water.
Nathan: You can't test for pH on RO/DI water with one of the pH probes that we normally use in the hobby. I think, however, that the multi thousand $$ lab grade pH probes will do the trick.
Indeed, carbon dioxide is absorbed from the air. But, say, you store AND make the RO water in a room without gasses ('air'). Than, the pH would be 7. Why? H2O is water, but, in the water there ALWAYS is a balance between H+ and OH-, these ions come from the water itself! And, add H+ to OH-, and you'll get water!